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Therefore, many reactions occur even under thermodynamically unfavorable conditions and would never occur in isolation, favoring the kinetic pathways and rates associated with certain reactions ( Thiols can produce disulfides in one or more thiol-disulfide exchange processes in intricate biological systems ( in vivo enzyme catalysis speeds up the events, spontaneous thiol-disulfide exchange is slow (kinetically inadequate on the folding timescale)
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